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Directed Vapor Deposition (DVD) is a novel physical vapor deposition
tool invented at the University of Virginia (UVA). It offers unique
advantages for applying a wide range of coatings onto components. DVD
utilizes specially modified electron-beam (e-beam) guns to vaporize
materials. The novel gun design allows DVD to operate in a low vacuum
environment (~10-3 - 10 Torr) where it is possible to entrain the
evaporant in a carrier gas jet for focused, efficient deposition.
The
original DVD system (DVD I) was designed and built at the
University of Virginia (UVA) from 1994-96 when researchers were posed
with a unique challenge. Develop a low cost means for coating extremely
small (0.1 mm diameter) ceramic fibers with a thick coating (also ~
0.1 mm thick) of a complex metal alloy. These researchers found that no
existing coating process enabled the process economy and control
required to be successful for this particular application. So they
invented a new process.
High speed electron beam evaporation was used to efficiently create
a dense vapor flux. To efficiently coat the small fibers a supersonic
gas jet was employed to tightly focus the vapor to closer match the
dimension of the fiber. This enabled much higher deposition rates the
previously possible making vapor deposition a suitable means to solving
their problem. Further research led to the discovery that by controlling
the flow of gas around the fiber a coating could be applied to not only
the front of the fiber, but also the sides and back. Intrigued by the
novel attributes of this processing approach a broad experimental and
modeling research initiative was undertaken resulting in a detailed
understanding of the fundamental material processing characteristics
of this approach.
Following the extensive study of the first generation concepts,
construction of a second generation system (DVD II) was completed in
2000 at UVA. DVD II again combined sophisticated low vacuum electron beam
(e-beam) evaporation with vapor transport in a flowing gas stream. However,
the new system design enabled more efficient use of the gas jet to
further enhance the utilization efficiency and deposition rate of
the process.
The new design also allowed the jet to be used to control the degree
of intermixing of elements that were simultaneously evaporated from
closely neighboring sources. This has allowed the formation precise
alloys compositions and enabled combinatorial synthesis approaches to
be applied to coating development. When evaporated sequentially,
multiple source evaporation has allowed the formation of multi-layer
coatings. Also new to this system was ability to plasma activate and
attract the gas and vapor atoms to an electrically biased coating
surface. The innovative combination of e-beam multi-source evaporation,
carrier gas transport, plasma activation, and biasing created in this
system opened up new possibilities for the creation of desirable film
structures and compositions.
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